Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.     

Rock slope stability and design in Arafat–Muzdalifa area,Saudi Arabia

The present contribution is a complete study extending before, during, and after the excavation of the mountain side that lying north of road 7. It includes slope stability analysis, rock cut design, and rockfall modeling for natural slope and rock cut face. Neoproterozoic granodiorite and biotite granite forming the slope body have medium to very high strengths. Mineral compositions and textures of these intact rocks control the strength values. These rocks are intensively dissected by fractures that are filled with montmorillonite and chlorite. The high plasticity and slippery nature of these filling materials represent the main problem that may face a rock cut designer because they damage the mechanical properties of these fractures. The problem begins with the selection of the rock mass classification that deals with the fracture fillings and extends during the stability analysis and the suggestion of mitigation and supporting measures. The rock masses building the natural slope are suffered by plane, wedge, and toppling failures. Therefore, two rock cut designs are suggested to avoid the hazards related to these failures and considering the construction cost as well. Rockfall modeling for the natural slope and rock cut designs was done to assess the hazards related to these falling of the blocks. The kinetic energy of falling blocks is represented on the roadway by the coverage distance and block rebound amplitude. Slope height has a positive effect on the values of these distance and amplitude, whereas the steepness of berm height has a negative effect on them. Coverage distance is a function to the location of rockfall barrier and to the width of road ditch, while the amplitude controls the barrier height.     

Petroleum system analysis of the Khatatba Formation in the Shoushan Basin,north Western Desert,Egypt

The Middle Jurassic Khatatba Formation is an attractive petroleum exploration target in the Shoushan Basin, north Western Desert, Egypt. However, the Khatatba petroleum system with its essential elements and processes has not been assigned yet. This study throws the lights on the complete Khatatba petroleum system in the Shoushan Basin which has been evaluated and collectively named the Khatatba-Khatatba (!) petroleum system. To evaluate the remaining hydrocarbon potential of the Khatatba system, its essential elements were studied, in order to determine the timing of hydrocarbon generation, migration and accumulation. Systematic analysis of the petroleum system of the Khatatba Formation has identified that coaly shales and organic-rich shales are the most important source rocks. These sediments are characterised by high total organic matter content and have good to excellent hydrocarbon generative potential. Kerogen is predominantly types II–III with type III kerogen. The Khatatba source rocks are mature and, at the present time, are within the peak of the oil window with vitrinite reflectance values in the range of 0.81 to 1.08 % Ro. The remaining hydrocarbon potential is anticipated to exist mainly in stratigraphic traps in the Khatatba sandstones which are characterised by fine to coarse grain size, moderate to well sorted. It has good quality reservoir with relatively high porosity and permeability values ranging from 1 to 17 % and 0.05–1,000 mD, respectively. Modelling results indicated that hydrocarbon generation from the Khatatba source rocks began in the Late Cretaceous time and peak of hydrocarbon generation occurred during the end Tertiary time (Neogene). Hydrocarbon primarily migrated from the source rock via fractured pathways created by abnormally high pore pressures resulting from hydrocarbon generation. Hydrocarbon secondarily migrated from active Khatatba source rocks to traps side via vertical migration pathways through faults resulting from Tertiary tectonics during period from end Oligocene to Middle Miocene times.     

Diagenesis in the Middle Jurassic Khatatba Formation sandstones in the Shoushan Basin,northern Western Desert,Egypt

The Middle Jurassic Khatatba Formation acts as a hydrocarbon reservoir in the subsurface in the Western Desert, Egypt. This study, which is based on core samples from two exploration boreholes, describes the lithological and diagenetic characteristics of the Khatatba Formation sandstones. The sandstones are fine‐ to coarse‐grained, moderately to well‐sorted quartz arenites, deposited in fluvial channels and in a shallow‐marine setting. Diagenetic components include mechanical and chemical compaction, cementation (calcite, clay minerals, quartz overgrowths, and a minor amount of pyrite), and dissolution of calcite cements and feldspar grains. The widespread occurrence of an early calcite cement suggests that the Khatatba sandstones lost a significant amount of primary porosity at an early stage of its diagenetic history. In addition to calcite, several different cements including kaolinite and syntaxial quartz overgrowth occur as pore‐filling and pore‐lining cements. Kaolinite (largely vermicular) fills pore spaces and causes reduction in the permeability of the reservoir. Based on framework grain–cement relationships, precipitation of the early calcite cement was either accompanied by or followed the development of part of the pore‐lining and pore‐filling cements. Secondary porosity development occurred due to partial to complete dissolution of early calcite cements and feldspar. Late kaolinite clay cement occurs due to dissolved feldspar and has an impact on the reservoir quality of the Khatatba sandstones. Open hydraulic fractures also generated significant secondary porosity in sandstone reservoirs, where both fractures and dissolution took place in multiple phases during late diagenetic stages. The diagenesis and sedimentary facies help control the reservoir quality of the Khatatba sandstones. Fluvial channel sandstones have the highest porosities and permeabilities, in part because of calcite cementation, which inhibited authigenic clays or was later dissolved, creating intergranular secondary porosity. Fluvial crevasse‐splay and marine sandstones have the lowest reservoir quality because of an abundance of depositional kaolinite matrix and pervasive, shallow‐burial calcite and quartz overgrowth cements, respectively. Copyright © 2013 John Wiley & Sons, Ltd.     

Compressive and Tensile Behavior of Polymer Treated Sulfate Contaminated CL Soil

In this study, the compressive and tensile behavior of polymer treated sulfate contaminated CL soil was investigated. Based on the information in the literature, a field soil was contaminated with up to 4 % (40,000 ppm) of calcium sulfate in this study. In addition to characterizing the behavior of sulfate contaminated CL soil, the effect of treating the soil with a polymer solution was investigated and the performance was compared to 6 % lime treated soil. In treating the soil, acrylamide polymer solution (15 g of polymer dissolved in 85 g of water) content was varied up to 15 % (by dry soil weight). Addition of 4 % calcium sulfate to the soil decreased the compressive and tensile strengths of the compacted soils by 22 and 33 % respectively with the formation of calcium silicate sulfate [ternesite Ca₅(SiO₄)₂SO₄)], magnesium silicate sulfate (Mg₅(SiO₄)₂SO₄) and calcium-magnesium silicate (merwinite Ca₃Mg(SiO₄)₂). With the polymer treatment the strength properties of sulfate contaminated CL soil was substantially improved. Polymer treated sulfate soils had higher compressive and tensile strengths and enhanced compressive stress–strain relationships compared to the lime treated soils. Also polymer treated soils gained strength more rapidly than lime treated soil. With 10 % of polymer solution treatment, the maximum unconfined compressive and splitting tensile strengths for 4 % of calcium sulfate soil were 625 kPa (91 psi) and 131 kPa (19 psi) respectively in 1 day of curing. Similar improvement in the compressive modulus was observed with polymer treated sulfate contaminated CL soil. The variation of the compacted compressive strength and tensile strength with calcium sulfate concentrations for the treated soils were quantified and the parameters were related to calcium sulfate content in the soil and polymer content. Compressive stress–strain relationships of the sulfate soil, with and without lime and polymer treatment, have been quantified using two nonlinear constitutive models. The constitutive model parameters were sensitive to the calcium sulfate content and the type of treatment.     

Parameters affect foaming and foam stability during foam drilling

The authors presented indoor practice experiments of parameters affect on foaming and foam stability. Experiments were carried out and special equipments were used to determine foaming and foam stability; tests were tabulated and charted. The effects of chemical and physical parameters on foaming and foam stability have been conducted.     

The motion of artificial satellites in the set of Eulerian redundant parameters

In this paper, the connections between orbit dynamics and rigid body dynamics are established throughout the Eulerian redundant parameters, the perturbation equations for any conic motion of artificial satellites are derived in terms of these parameters. A general recursive and stable computational algorithm is also established for the initial-value problem of the Eulerian parameters for satellites prediction in the Earth's gravitational field with axial symmetry. Applications of the algorithm are considered for the two cases of short and long term predictions. For the short-term prediction, we consider the problem of the final state prediction of some typical ballistic missiles in the geopotential model with zonal harmonic terms up to J ₃₆, while for the long-term prediction, we consider the perturbed J ₂ motion of Explorer 28 over 100 revolutions.     

Radiolarian biochronology of Mesozoic deep-water successions in NW Syria and Cyprus: implications for south-Tethyan evolution

ABSTRACT New radiolarian biostratigraphical data have shed light on the Mesozoic tectonic evolution of South-Tethys in the Baer–Bassit region of NW Syria. Radiolarian assemblages of Late Triassic, Middle Jurassic and Early Cretaceous age were extracted from radiolarites in five measured sections. The results are compared with published radiolarian ages from the Mamonia Complex, western Cyprus. These two areas are interpreted as preserved fragments of the conjugate margins of a small South Tethyan oceanic basin formed by Triassic rifting. In the southerly (i.e. Arabian) margin, proximal successions were dominated by shallow-water-derived carbonate, whereas distal successions reveal seamount-type alkaline/peralkaline volcanism, dated as both Late Triassic and Middle Jurassic–Early Cretaceous. Along the inferred northern margin (i.e. western Cyprus) proximal successions are dominantly terrigenous, whereas distal settings include Late Triassic oceanic crust and seamount-type lavas.     

A geochemical survey of thermal springs in western part ofRepublic of Yemen and their geothermometric characteristics

The high-mineral contents of some thermal waters are believed to have medicinal properties. Numerous spas and bathhouses might be built at these hot springs to take advantage of theses supposed healing properties such as skin diseases, rheumatism and so on. This paper is to find thermal reservoir and to classify the kinds of water. The majority of thermal springs are found discharging from igneous centers of Tertiary and Quaternary volcanic fields of the western Yemen (research area). Structurally these volcanisms are connected to N-NW faults that are parallel to the main Red Sea trend. Temperature and pH values of the thermal spring range 37℃-96℃, and 6.3-8.7 respectively. The Yemen/thermal waters indicate high variability in composition since they are ofNa (K) -CI, Na=HCO3 and Ca (Mg) =SO4 types, whereas the surficial waters have the typical worldwide Ca (Mg) -HCO3 composition. Different liquid phase geothermometers,such as SiO2, K^2/Mg and Na/K. Estimated reservoir temperatures ranging 70℃-140℃ perform equilibrium temperature evaluation of the thermal reservoirs.     

Evaluation of the Flow Measurement Performance of Compound Sharp-Crested Over-Fall Weirs and Optimized Discharge Measurement in Data Scarce Areas

Water Resources - The hydraulic relationships of flow through the weir of different common shapes were investigated in this study. The hydraulic performances of weirs were carried out...